50268-18-3Relevant academic research and scientific papers
Electroorganic Synthesis. Reductive Alkylation of Functionalized 1,2-Dithiole-3-thiones
Darchen, Andre,Berthelot, Pascal,Vaccher, Claude,Viana, M. Nazareth,Debaert, Michel,Burgot, Jean Louis
, p. 1603 - 1607 (2007/10/02)
Two-electron reduction of some substituted 1,2-dithiole-3-thiones 1 followed by alkylation of the dianionic intermediates leads through electrosynthesis to mixture of Z end E isomers of the corresponding substituted alkyl-(3-thioalkyl)-2-propenedithioates 2, 3 in satisfactory yield.The structure of those products was established by 13C and 1H nmr and mass spectroscopy.The isomers ratios were determined by nmr spectroscopy.
