502687-01-6Relevant academic research and scientific papers
Synthesis, stereostructure, and conformations of novel Bi- and trifunctional (+)-isomenthone derivatives
Gardiner, John M.,Crewe, Philip D.,Smith, Gillian E.,Veal, Kenneth T.,Pritchard, Robin G.,Warren, John E.
, p. 467 - 470 (2003)
(Matrix presented) Following protection, keto alcohols 4 [from (+)-isomenthone] undergo reduction to 1,3-diol 6 (S configuration at the new stereocenter). Organometallic C-nucleophiles add to the carbonyl with the same facial selectivity as hydride, provi
