502690-35-9Relevant academic research and scientific papers
Strategy for Enantio- and Diastereoselective Syntheses of All Possible Stereoisomers of 1,3-Polyol Arrays Based on a Highly Catalyst-Controlled Epoxidation of α,β-Unsaturated Morpholinyl Amides: Application to Natural Product Synthesis
Tosaki, Shin-Ya,Horiuchi, Yoshihiro,Nemoto, Tetsuhiro,Ohshima, Takashi,Shibasaki, Masakatsu
, p. 1527 - 1544 (2007/10/03)
We describe a new strategy for enantio- and diastereoselective syntheses of all possible stereoisomers of 1,3-polyol arrays. This strategy relies on a highly catalyst-controlled epoxidation of α,β-unsaturated morpholinyl amides promoted by the Sm-BINOL-Ph
Catalytic asymmetric synthesis of both syn- and anti-3,5-dihydroxy esters: application to 1,3-polyol/alpha-pyrone natural product synthesis.
Tosaki, Shin-Ya,Nemoto, Tetsuhiro,Ohshima, Takashi,Shibasaki, Masakatsu
, p. 495 - 498 (2007/10/03)
[reaction: see text] We describe a catalytic asymmetric synthesis of both syn- and anti-3,5-dihydroxy esters. The method relies upon catalytic asymmetric epoxidation of alpha,beta-unsaturated imidazolides and amides, using lanthanide-BINOL complexes, and
