502925-03-3

Upstream product

• 66324-50-3 Z-1-bromo-tridecene 
• 208935-32-4 (4S,trans)-4,5-dihydro-4-(tert-butyldimethylsilanyloxymethyl)-2-phenyloxazoline 
• 140200-05-1 tert-butyl (S)-1-(tert-butyldimethylsilyloxy)-3-oxopropan-2-yl carbamate 

Downstream Products

• 502925-04-4 (4S,5R)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-5-((Z)-pentadec-3-enyl)-2-phenyl-4,5-dihydro-oxazole 
• 502925-09-9 (4S,5R)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-5-pentadecyl-2-phenyl-4,5-dihydro-oxazole 
• 764-22-7 (2S,3R)-2-amino-1,3-octadecanediol 
• 502925-06-6 (4S,5S)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-5-pentadecyl-2-phenyl-4,5-dihydro-oxazole 

Relevant academic research and scientific papers

Stereoselective synthesis of D-erythro- and L-threo-sphinganines via palladium-catalyzed equilibration and Suzuki coupling

The Pd-catalyzed isomerization of 5-vinyloxazolines was utilized for the stereoselective synthesis of D-erythro- and L-threo-spinganine triacetate. A hydroboration/Suzuki coupling sequence was employed to elongate the hydrophobic chain.