503153-25-1Relevant articles and documents
Nonplanar aromatic compounds. 8.1 synthesis, crystal structures, and aromaticity investigations of the 1,n-dioxa[n](2,7)pyrenophanes. How does bending affect the cyclic π-electron delocalization of the pyrene system?
Bodwell, Graham J.,Bridson, John N.,Cyranski, Michal K.,Kennedy, Jason W. J.,Krygowski, Tadeusz M.,Mannion, Michael R.,Miller, David O.
, p. 2089 - 2098 (2003)
A series of 1,n-dioxa[n](2,7)pyrenophanes (n = 7-12) with increasingly nonplanar pyrene moieties was synthesized by a 9-10 step sequence starting from 5-hydroxyisophthalic acid. The crystal structure of each member of this series was determined crystallographically. Several spectroscopic properties were found to vary with the extent of the nonplanarity of the pyrene unit. The way in which the distortion from planarity of the pyrene system influences its π-electron delocalization was investigated by using two quantitative descriptors of aromaticity based on geometry (HOMA) and magnetism (magnetic susceptibility and NICS). Both methods suggest that the aromaticity of the pyrene moiety is diminished only slightly upon increasing the bend angle θ from 0° to 109.2°.
Ligand flexibility and framework rearrangement in a new family of porous metal-organic frameworks
Hawxwell, Samuel M.,Espallargas, Guillermo Minguez,Bradshaw, Darren,Rosseinsky, Matthew J.,Prior, Timothy J.,Florence, Alastair J.,Van De Streek, Jacco,Brammer, Lee
, p. 1532 - 1534 (2008/02/03)
Ligand flexibility permits framework rearrangement upon evacuation and gas uptake in a new family of porous MOFs. The Royal Society of Chemistry.
