503179-05-3Relevant articles and documents
Mixed metal clusters of iron and cobalt from carbonyl iron dichloro-phenylphosphine complexes with cyclopentadienyl cobaltdicarbonyl
De, Rajib Lal,Maiti, Kamales
, p. 2296 - 2299 (2007/10/03)
The reaction of CpCo(CO)2 with the monoiron carbonyl phosphine complexes, Fe(CO)4PPhCl2 and the two diiron carbonyl phosphine complexes, Fe2(CO)6(PPhCl)2, Fe2(CO)6(PPhCl2) have been studied which yields the heterometallic phosphorus bridged cluster molecules (CpCo)2Fe(CO)4PPh(1) and (CpCo)2Fe(CO)5PPh(2); (CpCo)2Fe(CO)3(PPh)2(4) and (CpCo)2Fe2(CO)5(PPh)2(5); CpCoFe2(CO)7PPh(6) and (CpCo)2Fe2(CO)5(PPh)2(7) respectively. A homometallic complex (CpCo)4(PPh)2(3) is also obtained as a side product from the reaction with Fe(CO)4PPhCl2 only. All the products have been characterised by the analytical data and IR. 1H-NMR and mass spectra.
