503273-40-3Relevant academic research and scientific papers
Stereocontrolled synthesis of bicyclic lactone derivatives via tungsten-mediated [3 + 2] cycloaddition of epoxides with a tethered alkynyl group
Madhushaw, Reniguntala J.,Li, Chien-Le,Su, Haw-Lih,Hu, Chu-Chen,Lush, Shie-Fu,Liu, Rai-Shung
, p. 1872 - 1877 (2003)
In the presence of BF3·Et2O, alkynyltungsten complexes underwent [3 + 2] cycloaddition with tethered epoxides to give bicyclic γ-lactones efficiently. Only one diastereomeric product was formed despite the presence of three stereogen
