503311-37-3

Upstream product

• 438547-22-9 3-Benzyloxy-5-nitro-4-trifluoromethanesulfonyloxy-benzoic acid methyl ester 
• 360562-49-8 5-[(tert-Butyldimethylsilyl)oxy]-1,2-dideoxy-3,4-O-(1-methylethylidene)-L-threo-pent-1-yne 

Downstream Products

• 503867-75-2 methyl 3-benzyloxy-4-[(2S,3R,4S)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-4-(toluene-4-sulfonyl)oxy-2-triisopropylsilyloxypentyl]-5-nitrobenzoate 
• 503867-73-0 methyl 3-benzyloxy-4-[(2S)-2-[(4R,5S)-5-(tert-butyldimethylsilyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-triisopropylsilyloxyethyl]-5-nitrobenzoate 
• 503867-74-1 methyl 3-benzyloxy-4-[(2S,3R,4S)-5-(tert-butyldimethylsilyloxy)-3,4-dihydroxy-2-triisopropylsilyloxypentyl]-5-nitrobenzoate 
• 503311-44-2 methyl 3-benzyloxy-4-[(2S)-2-[(2R,3R)-3-(tert-butyldimethylsilyloxymethyl)oxiran-2-yl]-2-triisopropylsilyloxyethyl]-5-nitrobenzoate 
• 503311-42-0 methyl 3-benzyloxy-5-nitro-4-[(2S,3R,4S)-3,4,5-trihydroxy-2-triisopropylsilyloxypentyl]benzoate 
• 503867-77-4 7-benzyloxy-3-(1-methoxy-1-methyl-ethoxy)-9-triisopropylsilanyloxy-1a,2,3,8,9,9a-hexahydro-1-oxa-3-aza-benzo[a]cyclopropa[e]cyclooctene-5-carboxylic acid methyl ester 
• 503311-39-5 3-Benzyloxy-4-{2-[(4R,5S)-5-(tert-butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2-oxo-ethyl}-5-nitro-benzoic acid methyl ester 
• 503311-52-2 methyl 3-benzyloxy-4-{(2S)-2-[(4S,5S)-5-(tert-butyldimethylsilyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-hydroxyethyl}-5-nitrobenzoate 
• 503311-45-3 methyl 3-benzyloxy-4-[(2S)-2-[(2R,3R)-3-hydroxymethyloxiran-2-yl]-2-triisopropylsilyloxyethyl]-5-nitrobenzoate 
• 503311-47-5 7-benzyloxy-3-hydroxy-9-triisopropylsilanyloxy-1a,2,3,8,9,9a-hexahydro-1-oxa-3-aza-benzo[a]cyclopropa[e]cyclooctene-5-carboxylic acid methyl ester 
• 503867-76-3 methyl 3-benzyloxy-4-[(2S)-2-[(2R,3R)-3-formyloxiran-2-yl]-2-triisopropylsilyloxyethyl]-5-nitrobenzoate 
• 503867-79-6 7-benzyloxy-8-hydroxymethyl-3-(1-methoxy-1-methyl-ethoxy)-9-oxo-1a,2,3,8,9,9a-hexahydro-1-oxa-3-aza-benzo[a]cyclopropa[e]cyclooctene-5-carboxylic acid methyl ester 
• 503311-53-3 7-benzyloxy-9-hydroxy-3-(1-methoxy-1-methyl-ethoxy)-1a,2,3,8,9,9a-hexahydro-1-oxa-3-aza-benzo[a]cyclopropa[e]cyclooctene-5-carboxylic acid methyl ester 
• 503311-49-7 7-benzyloxy-3-(1-methoxy-1-methyl-ethoxy)-9-oxo-1a,2,3,8,9,9a-hexahydro-1-oxa-3-aza-benzo[a]cyclopropa[e]cyclooctene-5-carboxylic acid methyl ester 

Relevant academic research and scientific papers

Facile construction of N-hydroxybenzazocine: Enantioselective total synthesis of (+)-FR900482

Intramolecular hydroxylamination of ω-formyl nitrobenzene 1 followed by stereoselective hydroxymethylation led to the formation of N-hydroxybenzazocine 2, a key intermediate in the enantioselective total synthesis of the antitumor antibiotic FR900482 (3).