503442-15-7

Basic information

• Product Name: N,N'-(bis-(pyridin-2-yl)benzylidene)diethylenetriamine
• CAS NO: 503442-15-7
• Molecular Weight: 433.556
• Mol File: 503442-15-7.mol

Chemical Properties

• CAS DataBase Reference: N,N'-(bis-(pyridin-2-yl)benzylidene)diethylenetriamine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N'-(bis-(pyridin-2-yl)benzylidene)diethylenetriamine(503442-15-7)
• EPA Substance Registry System: N,N'-(bis-(pyridin-2-yl)benzylidene)diethylenetriamine(503442-15-7)

Safety Data

• Hazardous Substances Data: 503442-15-7(Hazardous Substances Data)

Upstream product

• 91-02-1 phenyl(pyridin-2-yl)methanone 
• 111-40-0 3-azapentane-1,5-diamine 

Downstream Products

• 871239-98-4 Cd(N,N'-bis((2-pyridyl)benzylidene)diethylenetriamine)(NCS)ClO₄) 
• 1308859-92-8 [Cd(N,N'-(bis(pyridin-2-yl)benzylidene)diethylenetriamine)bromide] hexafluorophosphate * acetonitrile 
• 1257345-09-7 [manganese(II)(N,N'-bis(pyridin-2-yl)benzylidene)diethylenetriamine)(dicyanamide)](perchlorate) 
• 1257345-10-0 [manganese(II)(N,N'-bis(pyridin-2-yl)benzylidene)diethylenetriamine)(dicyanamide)](PF₆) 
• 1208170-67-5 [Cd(dicyanamide)(N,N'-(bis-(pyridin-2-yl)benzylidene)diethylenetriamine)](n)(ClO₄)(n) 
• 1208170-68-6 [Cd(dicyanamide)(N,N'-(bis-(pyridin-2-yl)benzylidene)diethylenetriamine)](n)[PF₆](n) 
• 748186-87-0 Mn(((C₆H₅)(C₅H₄N)CNCH₂CH₂)2NH)(N₃)⁽¹⁺⁾*ClO₄^(1-)=[Mn(((C₆H₅)(C₅H₄N)CNCH₂CH₂)2NH)(N₃)][ClO₄] 

Relevant articles and documents

Synthesis, structure and luminescence behaviour of heptacoordinated one-dimensional coordination polymers of the type [Cd(L)(dca)]n(X)n (L = a pentadentate Schiff base; dca = dicyanamide; X =ClO4-, PF6-)

Two heptacoordinated one-dimensional coordination polymers of the type [Cd(L)(dca)]n(X)n (1 and 2) [L = N,N′-(bis-(pyridin-2-yl)benzylidene)diethylenetriamine; dca = dicyanamide; X =ClO4- (1), PF6- (2)] have been prepared and characterized on the basis of microanalytical, spectroscopic and other physicochemical properties. Structures of 1 and 2 are solved by single crystal X-ray diffraction measurements. Structural study reveals that in both compounds each cadmium(II) center adopts a distorted pentagonal bipyramidal geometry with a CdN7 chromophore coordinated by five N atoms of the pentadentate Schiff base and two nitrile N atoms of single bridged dca in μ1,5 fashion. The polynuclear units in 1 are engaged in weak N-H...O and C-H...O hydrogen bondings with perchlorate ions embedded among the chains to give a 2D sheet structure. In the long-range form, the 1D polymeric chains of 2 pack through N-H...F and C-H...F hydrogen bonds with hexafluorophosphate placed in between chains resulting a 2D continuum. The complexes display intraligand 1(π-π*) fluorescence in DMF solutions at room temperature.