503446-29-5Relevant articles and documents
Efficient synthesis of [2H2]-tetrahydrodicranenone B and a 3-oxa-analogue resistant against β-oxidation
Lauchli, Ryan,Boland, Wilhelm
, p. 149 - 153 (2007/10/03)
A short efficient synthesis of two analogues of tetrahydrodicranenone B as well as a formal synthesis of tetrahydrodicranenone B (1) itself has been devised. The approach is based on an addition/elimination sequence of in situ prepared organocuprates to the iodocyclopentenone (9). The procedure is compatible with functionalised substituents.