50347-72-3Relevant academic research and scientific papers
Convenient preparation of N-monosubstituted S,S-diarylsulfodiimides using fluoro-λ6-sulfanenitriles
Yoshimura, Toshiaki,Ishikawa, Hiroki,Fujie, Tetsuo,Takata, Eiichi,Miyatake, Ryuta,Kita, Hiroshi,Tsukurimichi, Eiichi
experimental part, p. 1835 - 1840 (2009/04/04)
The reaction of fluorodiphenyl-λ6-sulfanenitrile with primary alkyl- or aryl-amines in the presence of acid catalysts or tertiary amines gave N-monosubstituted S,S-diphenylsulfodiimides effectively.
Synthesis and reactivity of S-sulfiliminothiazynes
Ohkubo, Masanori,Fujii, Takayoshi,Ono, Shin,Morita, Hiroyuki,Yoshimura, Toshiaki,Horn, Ernst,Sato, Soichi
, p. 153 - 154 (2007/10/03)
Reaction of S,S-diphenyl-S-fluorothiazyne with N-unsubstituted S,S-diphenylsulfilimine afforded the corresponding S-sulfiliminothiazyne. Measurement of the pKa value of S-sulfiliminothiazyne and its reactivity were examined. The molecular structure of the sulfonediiminosulfonium salt was determined by the X-ray crystallographic analysis.
First Preparation and Reactions of S,S-Diaryl-S-fluorothiazynes, Ar2SF(N)
Yoshimura, Toshiaki,Kita, Hiroshi,Takeuchi, Kyu,Takata, Eiichi,Hasegawa, Kiyoshi,et al.
, p. 1433 - 1436 (2007/10/02)
S,S-Diaryl-S-fluorothiazynes, Ar2SF(N), were prepared by the reaction of S,S-diaryl-N-bromosulfilimines with tetrabutylammonium fluoride.The thiazyne structure was assigned by the spectral data, physical properties, and is consistent with reactions wit
CONVENIENT PREPARATION AND SPECTROSCOPIC STUDIES OF SULFOXIMINES AND SULFONEDIIMINES: N-CHLOROSULFILIMINE AS KEY INTERMEDIATE
Furukawa, Naomichi,Akutagawa, Kunihiko,Oae, Shigeru
, p. 1 - 14 (2007/10/02)
N-Unsubstituted sulfilimines, when reacted with sodium hypochlorite in an aqueous alkaline methanol solution or with Chloramine-T in dry acetonitrile in the presence of excess sodium salt of tosylamide were converted to the corresponding N-unsubstituted s
