503552-70-3Relevant academic research and scientific papers
Heterogeneous Pd-catalyzed asymmetric allylic substitution using resin-supported Trost-type bisphosphane ligands
Song, Choong Eui,Yang, Jung Woon,Roh, Eun Joo,Lee, Sang-Gi,Ahn, Jou Hyeon,Han, Hogyu
, p. 3852 - 3854 (2007/10/03)
Easy recovery and reutilization of the catalyst in consecutive reactions: These are the advantages offered by a new class of polymer-bound Trost-type ligands (see Figure; is a polystyrene-based resin or JandaJEL). A complex is formed with [{(η3-C3H5)PdCl}2] that catalyzes asymmetric allylic substitutions with excellent activity and enantioselectivity (up to 99% ee).
