503559-53-3

Upstream product

• 7766-49-6 1-iodo-10-undecene 
• 135-77-3 1,2,4-trimethoxy-benzene 
• 112-43-6 10-Undecen-1-ol 

Downstream Products

• 503559-65-7 2-methylpenta-2,4-dienoic acid (2,4,5-trimethoxy-3-undec-10-enylphenyl)amide 
• 503559-61-3 2,4,5-trimethoxy-3-undec-10-enylphenylamine 
• 503559-57-7 1,2,4-trimethoxy-5-nitro-3-undec-10-enylbenzene 

Relevant academic research and scientific papers

Synthesis of a para-quinone macrolactam related to geldanamycin by ring closing metathesis

Model studies conducted with the α,β,γ,δ-unsaturated 3-alkenyl-2,4,5-trimethoxyanilides 11 revealed that a ring closing metathesis (RCM) of these compounds is possible if the ansa chain contains more than 14 atoms. The (Z)-configurated products 12c-e were

Synthesis of ansa-bridged macrocyclic lactams related to the antitumor antibiotic geldanamycin by ring closing metathesis

The α,β,γ,δ-unsaturated 2,4,5-trimethoxyanilides 8a-e which bear a terminal alkenyl side chain at the 3-position were prepared from 1,2,4-trimethoxybenzene (2) in four steps and 25-41% overall yield. Attempted ring closing metathesis reactions were succes