503559-55-5

Basic information

• Product Name: 1,2,4-trimethoxy-3-tridec-12-enylbenzene
• Synonyms: 1,2,4-trimethoxy-3-tridec-12-enylbenzene
• CAS NO: 503559-55-5
• Molecular Weight: 348.526
• Mol File: 503559-55-5.mol

Chemical Properties

• CAS DataBase Reference: 1,2,4-trimethoxy-3-tridec-12-enylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,4-trimethoxy-3-tridec-12-enylbenzene(503559-55-5)
• EPA Substance Registry System: 1,2,4-trimethoxy-3-tridec-12-enylbenzene(503559-55-5)

Safety Data

• Hazardous Substances Data: 503559-55-5(Hazardous Substances Data)

Upstream product

• 16339-75-6 12-tridecenyl alcohol 
• 135-77-3 1,2,4-trimethoxy-benzene 
• 503559-71-5 13-iodotridec-1-ene 

Downstream Products

• 792921-52-9 2-methyl-pent-4-enoic acid (2,4,5-trimethoxy-3-tridec-12-enyl-phenyl)-amide 
• 503559-67-9 2-methylpenta-2,4-dienoic acid (2,4,5-trimethoxy-3-tridec-12-enylphenyl)amide 
• 503559-63-5 2,4,5-trimethoxy-3tridec-12-enylphenylamine 
• 503559-59-9 1,2,4-trimethoxy-5-nitro-3-tridec-12-enylbenzene 

Relevant articles and documents

Synthesis of ansa-bridged macrocyclic lactams related to the antitumor antibiotic geldanamycin by ring closing metathesis

The α,β,γ,δ-unsaturated 2,4,5-trimethoxyanilides 8a-e which bear a terminal alkenyl side chain at the 3-position were prepared from 1,2,4-trimethoxybenzene (2) in four steps and 25-41% overall yield. Attempted ring closing metathesis reactions were succes

Synthesis of a para-quinone macrolactam related to geldanamycin by ring closing metathesis

Model studies conducted with the α,β,γ,δ-unsaturated 3-alkenyl-2,4,5-trimethoxyanilides 11 revealed that a ring closing metathesis (RCM) of these compounds is possible if the ansa chain contains more than 14 atoms. The (Z)-configurated products 12c-e were