503570-30-7

Basic information

• Product Name: ethyl 3-(2-azido-1-hydroxy-1-methylethyl)-2-oxocyclohexanecarboxylate
• Synonyms: ethyl 3-(2-azido-1-hydroxy-1-methylethyl)-2-oxocyclohexanecarboxylate
• CAS NO: 503570-30-7
• Molecular Weight: 269.301
• Mol File: 503570-30-7.mol

Chemical Properties

• CAS DataBase Reference: ethyl 3-(2-azido-1-hydroxy-1-methylethyl)-2-oxocyclohexanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 3-(2-azido-1-hydroxy-1-methylethyl)-2-oxocyclohexanecarboxylate(503570-30-7)
• EPA Substance Registry System: ethyl 3-(2-azido-1-hydroxy-1-methylethyl)-2-oxocyclohexanecarboxylate(503570-30-7)

Safety Data

• Hazardous Substances Data: 503570-30-7(Hazardous Substances Data)

Upstream product

• 4504-27-2 1-azidopropan-2-one 
• 1655-07-8 ethyl 2-oxocyclohexane carboxylate 

Relevant articles and documents

Efficient and regioselective synthesis of functionalized pyrroles by cyclocondensation of 1,3-dicarbonyl dianions with α-azidoketones

The cyclocondensation of 1,3-dicarbonyl dianions with α-azidoketones regioselectively afforded 2-alkylidenepyrrolidines which were transformed into functionalized pyrroles by treatment with acid.

Synthesis of 2-alkylidenepyrrolidines and pyrroles by condensation of 1,3-dicarbonyl dianions with α-azidoketones and subsequent intramolecular Staudinger-aza-Wittig reaction

The condensation of 1,3-dicarbonyl dianions with α-azidoketones afforded open-chained condensation products that were transformed into pyrroles by Staudinger-aza-Wittig reactions and the subsequent treatment with trifluoroacetic acid.