503595-80-0Relevant academic research and scientific papers
Transition-Metal-Free Synthesis of Ynones via Decarboxylative Alkynylation of α-Keto Acids under Mild Conditions
Wang, Peng-Fei,Feng, Yi-Si,Cheng, Zhi-Fei,Wu, Qiu-Min,Wang, Guang-Yu,Liu, Liang-Liang,Dai, Jian-Jun,Xu, Jun,Xu, Hua-Jian
, p. 9314 - 9320 (2015/09/28)
A transition-metal-free synthetic method of various ynones via decarboxylative alkynylation of α-keto acids is described. The reaction is carried out under mild conditions and exhibits remarkable tolerance of functional groups. The mechanism of a radical
An extremely facile aza-Bergman rearrangement of sterically unencumbered acyclic 3-aza-3-ene-1,5-diynes
Feng, Liping,Kumar, Dalip,Kerwin, Sean M.
, p. 2234 - 2242 (2007/10/03)
The factors that affect the kinetics of the aza-Bergman cyclization of aza-enediynes (C,N-dialkynyl imines) have not previously been elucidated. Here we report our kinetic studies of the aza-Bergman reactions of a series of 6-triisopropylsilyl and 6-unsub
