503624-12-2

Upstream product

• 28790-87-6 ethyl 1,2-dimethyl-4-oxocyclohex-2-ene-1-carboxylate 

Downstream Products

• 503624-15-5 ethyl 5-bromo-1-methyl-4-oxo-2-(4-trimethylsilylfuran-3-yl)methylcyclohex-2-ene-1-carboxylate 
• 503624-16-6 ethyl 1-methyl-4-oxo-2-(4-trimethylsilylfuran-3-yl)methylcyclohex-2-ene-1-carboxylate 
• 503624-17-7 ethyl 1-methyl-4-hydroxy-2-(4-trimethylsilylfuran-3-yl)methylcyclohex-2-ene-1-carboxylate 
• 503624-23-5 ethyl 5-bromo-1-methyl-4-oxo-2-(4-methylfuran-3-yl)methylcyclohex-2-ene-1-carboxylate 
• 503624-25-7 ethyl 1-methyl-4-hydroxy-2-(4-methylfuran-3-yl)methylcyclohex-2-ene-1-carboxylate 
• 503624-24-6 ethyl 1-methyl-4-oxo-2-(4-methylfuran-3-yl)methylcyclohex-2-ene-1-carboxylate 

Relevant academic research and scientific papers

Regiospecific substitution of the carbon-boron bond of tris(4-trimethylsilylfuran-3-yl)boroxine and tris(4-methylfuran-3-yl)boroxine. Model approaches towards sesquiterpenoid furanoeudesmanes

Furan-containing compounds occur abundantly in nature. Among them, the sesquiterpenoid furanoeudesmanes are particularly interesting due to their allergenic, plant-growth inhibiting, antibacterial as well as antitumor properties. Recently an organoboron protocol has been developed in our laboratory for the preparation of regiospecific-substituted furans. By utilizing such methodology, two common intermediates 1 and 2 that may lead to the synthesis of naturally occurring tubipofuran (3) furanoeudesm-4-ene (4) and furanoeudesma-1,4-dien-6-one (5) were obtained.