503822-36-4

Upstream product

• 6630-33-7 ortho-bromobenzaldehyde 
• 503822-33-1 (R)-2-(allylamino)-2-phenylethanol 
• 56613-80-0 D-2-phenylglycinol 

Downstream Products

• 503822-39-7 (3R,6R)-6-methyl-3-phenyl-2,3,6,10b-tetrahydro-5H-oxazolo[2,3-a]isoquinoline 
• 503822-42-2 (3R)-3-phenyl-2,3,4,5,6,10b-hexahydro-1-oxo-3a-azabenzo[e]azulene 
• 503822-51-3 (1S,1'R,4R)-1,4-dimethyl-2-(2'-hydroxy-1'-phenylethyl)-1,2,3,4-tetrahydroisoquinoline 
• 503822-45-5 (1'R,4S)-2-(2'-hydroxy-1'-phenylethyl)-4-methyl-1,2,3,4-tetrahydroisoquinoline 
• 350508-38-2 (R)-4-methyl-1,2,3,4-tetrahydroisoquinoline 

Relevant academic research and scientific papers

Stereoselective synthesis of pyrrolidines from N-allyl oxazolidines via hydrozirconation-cyclization

(Chemical Equation Presented) A new diastereoselective synthesis of pyrrolidines from readily available chiral N-allyl oxazolidines is presented. The construction of the pyrrolidine ring is achieved via a tandem hydrozirconation-stereoselective Lewis acid

Aryl radical cyclization of chiral 3-allyl-2-(2-bromophenyl)-1,3-oxazolidines with tributyltin hydride

Stereoselective radical cyclization of (4R)-3-allyl-2-(2-bromophenyl)-4-phenyl-1,3-oxazolidine promoted by the initiator/tributyltin hydride system constructed the chiral oxazolo[2,3-a]tetrahydroisoquinoline skeleton. These tricyclic compounds were transf