50423-50-2Relevant academic research and scientific papers
1,1-vs. 1,6-Dehalogenation in gem-Dibromocyclopropanes. Synthesis of Benzo-anti-?-bishomobenzene
Brinker, Udo H.,Wuester, Hartmut,Maas, Gerhard
, p. 1812 - 1814 (2007/10/02)
The bisdibromocarbene adduct (9a) on treatment with methyl-lithium at temperatures below ca. -50 deg C undergoes a ring-closure reaction by 1,6-elimination to give after reduction anti-?-bishomobenzene (11); above -50 deg C products derived from 1,1-elimi
