50474-30-1Relevant academic research and scientific papers
Improved Synthesis of Secondary Hydroperoxides from Alcohols
Casteel, Dee Ann,Jung, Kyeong-Eun
, p. 2597 - 2598 (1991)
Secondary hydroperoxides have been prepared from secondary alcohols by conversion of the alcohol into its mesylate and subsequent reaction with anhydrous hydrazine followed by hydrogen peroxide and sodium peroxide.
NITRONE CYCLOADDITIONS WITH VINYL SILANES: THE TOTAL SYNTHESIS OF DEOXYSUGARS.
DeShong, Philip,Leginus, Joseph M.
, p. 5355 - 5358 (2007/10/02)
The total synthesis of (+/-)-rhodinose (2) and benzoxocin 4, a model system for the glycosidic moiety of nogalomycin, are reported.The key transformation in each reaction sequence involves the cycloaddition of a nitrone with vinyltrimethylsilane to produc
