505087-61-6Relevant articles and documents
Gold-catalyzed oxidative reactions of propargylic carbonates involving 1,2-carbonate migration: Stereoselective synthesis of functionalized alkenes
Sun, Ning,Chen, Ming,Liu, Yuanhong
, p. 4055 - 4067 (2014/05/20)
A gold-catalyzed oxidative reaction of propargylic carbonates or acetates using 3,5-dichloropyridine as the oxidant has been developed. The reaction provides efficient access to α-functionalized-α,β-unsaturated ketones with excellent regio- and diastereoc
Asymmetric palladium-catalyzed annulation of benzene-1,2-diol and racemic secondary propargylic carbonates bearing two different substituents
Dominczak, Norbert,Damez, Céline,Rhers, Bouchra,Labrosse, Jean-Robert,Lhoste, Paul,Kryczka, Boguslaw,Sinou, Denis
, p. 2589 - 2599 (2007/10/03)
The palladium-catalyzed cyclization of benzene-1,2-diol with various racemic secondary propargyl carbonates having no acetylenic hydrogen in the presence of (R)-Binap as the chiral ligand afforded the two regioisomers of the corresponding 2,3-dihydro-1,4-