505094-72-4Relevant academic research and scientific papers
Is fluoride bonded to two Pd acceptors still basic? Three CH2Cl2 molecules encapsulating a Pd2(μ-F)2 square and new implications for catalysis
Grushin, Vladimir V.,Marshall, William J.
, p. 4476 - 4479 (2007/10/03)
The unexpectedly high basicity of bridging fluoride ions in novel dinuclear Pd complexes is manifested by intramolecular CH...F interactions and the unprecedented hydrogen bonding of three CH2Cl2 molecules to the Pd2F2 framework (see scheme). Novel deprotonation of a coordinated (alkyl)3P ligand to produce a bifluoride is reported.
