50518-29-1Relevant articles and documents
TRIHYDRIDOSILYL-TERMINATED POLYSILANES AND METHODS OF PREPARATION
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Page/Page column 5-6, (2012/04/04)
Novel trihydridosilyl-terminated polysilanes and methods for their synthesis, which are applicable to other polysilanes, are provided. The synthetic methods provide for facile preparation of products with minimal handling of pyrophoric intermediates and b
Electrochemical synthesis of symmetrical difunctional disilanes as precursors for organofunctional silanes
Grogger, Christa,Loidl, Bernhard,Stueger, Harald,Kammel, Thomas,Pachaly, Bernd
, p. 105 - 110 (2007/10/03)
Difunctional disilanes of the general type XR2SiSiR2X (1-5) (X = OMe, H; R = Me, Ph, H) have been synthesized by electrolysis of the appropriate chlorosilanes XR2SiCl in an undivided cell with a constant current supply and in the absence of any complexing agent. Reduction potentials of the chlorosilane starting materials derived from cyclic voltammetry measurements were used to rationalize the results of preparative electrolyses. Organofunctional silanes of the general formula MeO(Me 2)SiC6H4Y (6a-c, 7) were subsequently obtained by the reaction of sym-dimethoxytetramethyldisilane (1) with NaOMe in the presence of p-functional aryl bromides BrC6H4Y (Y = OMe, NEt2, NH2).
Rapid, highly linear-selective dehydrocoupling of phenylsilane with new group 4 metallocene-based combination catalysts
Woo, Hee-Gweon,Song, Sun-Jung
, p. 457 - 458 (2007/10/03)
The dehydrocoupling of phenylsilane with Cp12MCl2/Red-Al (Cp1 = C5H5 or C5Me5; M = Ti, Zr, Hf; Red-Al = Na[H2Al(OCH2CH2OMe)2/sub