50525-40-1Relevant academic research and scientific papers
Synthesis, structural characterization and biological screening of heteroleptic palladium(II) complexes
Khan, Hizbullah,Badshah, Amin,Said, Muhammad,Murtaza, Ghulam,Sirajuddin, Muhammad,Ahmad, Jamil,Butler, Ian S.
, p. 176 - 182 (2016/05/09)
Heteroleptic palladium(II) complexes of the type formula [(DTC)(Pd)(PR3)Cl], where DTC = bis(2-ethylhexyl)dithiocarbamate (1, 8, 9, 10), bis(2-methoxyethyl)dithiocarbamate (2), di-n-decyldithiocarbamate (3, 6), di-n-hexyldithiocarbamate (4, 7), bis(2-methylbutyl)dithiocarbamte (5); PR3 = diphenyl-t-butylphosphine (1), diphenyl-n-propylphosphine (2), triphenylphosphine (3, 4, 5, 10), diphenyl-p-tolylphosphine (6, 7, 8), diphenylbenzylphosphine (9); have been synthesized and characterized by FTIR, Raman, multinuclear and multinuclear NMR (1H, 13C, 31P) spectroscopy and elemental analyses. The structures of complexes (1 and 2) were determined by single-crystal X-ray diffraction. The geometries around the metal centers are pseudo square-planar. The new complexes exhibit moderate anticancer and antibacterial activity.
