50540-30-2

Basic information

• Product Name: octaethylporphyrinatoiron(III)perchlorate
• Synonyms: octaethylporphyrinatoiron(III)perchlorate
• CAS NO: 50540-30-2
• Molecular Formula: C₃₆H₄₄ClFeN₄O₄
• Molecular Weight: 688.07
• Mol File: 50540-30-2.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 804.9°C at 760 mmHg
• Flash Point: 335.1°C
• Appearance: /
• Vapor Pressure: 6.24E-25mmHg at 25°C
• CAS DataBase Reference: octaethylporphyrinatoiron(III)perchlorate(CAS DataBase Reference)
• NIST Chemistry Reference: octaethylporphyrinatoiron(III)perchlorate(50540-30-2)
• EPA Substance Registry System: octaethylporphyrinatoiron(III)perchlorate(50540-30-2)

Safety Data

• Hazardous Substances Data: 50540-30-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C36H44N4.ClHO4.Fe/c1-9-21-22(10-2)30-18-32-25(13-5)26(14-6)34(39-32)20-36-28(16-8)27(15-7)35(40-36)19-33-24(12-4)23(11-3)31(38-33)17-29(21)37-30;2-1(3,4)5;/h17-20H,9-16H2,1-8H3;(H,2,3,4,5);/q-2;;+3/p-1/b29-17-,30-18-,31-17-,32-18-,33-19-,34-20-,35-19-,36-20-;;

Upstream product

• 1365453-15-1 [Fe(octaethylporphyrin)(piperazine)2][ClO₄] 
• 1365453-20-8 [Fe(octaethylporphyrin)(piperidine)2][ClO₄] 
• 1365453-25-3 [Fe(octaethylporphyrin)(pyrrolidine)2][ClO₄] 

Downstream Products

• 89596-92-9 (OEP)Fe(NO)⁽¹⁺⁾ 
• 111436-54-5 {(octaethylporphyrin)FeClO₄}⁽¹⁺⁾ 
• 61085-06-1 {(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(II)} 
• 83614-07-7 {(C₂₀H₄(C₂H₅)8N₄)Fe(C₆H₄OCH₃)} 
• 83614-06-6 (2,3,7,8,12,13,17,18-tetraethylporphyrinato)Fe(III)(C₆H₅) 
• 83614-08-8 (octaethylporphyrin)Fe(p-MeC₆H₄) 

Relevant articles and documents

Axial ligation of iron(III) porphyrin with a series of aliphatic bases: Piperazine, piperidine and pyrrolidine

The binding of a series of nitrogen donor ligands (Piperazine (Pipz), Piperidine (Pip) and Pyrro- lidine (Pyr)) to iron porphyrin, OEPFeClO 4, where OEP is octaethylporphyrin, has been characterized by electronic spectroscopy in CH2Cl2. In nonaqueous media, in the presence of a neutral ligand, the equilibria observed are: OEPFeClO 4 + 2L [OEPFeL2]+ (β2) where the product is an ion pair and in some cases: OEPFeClO4 + L OEPFeLClO4 (K1), where the product may either be the six-coordinate or the five-coordinate [OEPFeL]+ ion pair, that L denotes neutral N-donor ligands. This behavior for the nitrogen donor ligands (L = Pipz, Pip, Pyr) is confirmed by spectrophotometric titrations data and the bind- ing constants for the substitution reaction have been reported. Pleiades Publishing, Ltd., 2012.