5055-11-8Relevant academic research and scientific papers
Self-Assembly and Aggregation-Induced Emission in Aqueous Media of Responsive Luminescent Copper(I) Coordination Polymer Nanoparticles
Hernández-Toledo, Hugo,Torrens, Hugo,Flores-álamo, Marcos,De Cola, Luisa,Moreno-Alcántar, Guillermo
supporting information, p. 8308 - 8314 (2021/05/21)
Luminescent copper(I)-based compounds have recently attracted much attention since they can reach very high emission quantum yields. Interestingly, Cu(I) clusters can also be emissive, and the extension from small molecules to larger architecture could re
Reversible carbon monoxide binding at copper(I) P-S-X (X = N, O) coordination polymers
Tate, Christopher W.,Gee, Antony D.,Vilar, Ramon,White, Andrew J.P.,Long, Nicholas J.
experimental part, p. 39 - 42 (2012/09/07)
Reaction of Ph2PCH2CH2S(2-C 6H4NH2) (1) or Ph2PCH 2CH2S(2-C6H4OMe) (2) with CuCl and AgSbF6 in the presence of THF affords
Phosphino-indenyl complexes of nickel(II)
Groux, Laurent F.,Belanger-Gariepy, Francine,Zargarian, Davit
, p. 634 - 639 (2007/10/03)
The BH3-protected phosphinoindenyl ligand indenyl(CH 2)2PPh2·BH3 was used in the preparation of (η5/3:η0-indenyl(CH 2)2PPh2·BH3)Ni(PPh 3)Cl, which has been characterized by NMR spectroscopy and X-ray diffraction studies. On the other hand, all attempts at preparing the closely related complex (η5/3:η1indenyl(CH 2)2PPh2)NiCl, in which the tethered phosphine moiety is coordinated to the Ni centre, were unsuccessful. One of these unsuccessful attempts yielded instead the novel indenyl-PCP pincer complex {KP,KC,KP-1,3-(CH2CH 2PPh2)2-2-indenyl}NiCl, which has been characterized by X-ray diffraction studies.
Synthesis of a new family of water-soluble tertiary phosphine ligands and of their rhodium(I) complexes; olefin hydrogenation in aqueous and biphasic media
Renaud, Eric,Russell, Robert B.,Fortier, Suzanne,Brown, Stephen J.,Baird, Michael C.
, p. 403 - 415 (2007/10/02)
The series of phosphonium phosphines (Ph2P(CH2)nPMe3>X (n = 2, 3, 6, 10; N = NO3-, Cl-, PF6-), henceforth II-, III-, VI- and X-phosphos respectively, have been prepared and characterized.The ligands react with 2 (NBD = norbornadiene) to form the complexes X, one of which, PF6, has been characterized crystallographically.The 1:1 complexes X react with a second equivalent of ligand to form the complexes X, which form very active olefin hydrogenation catalysts in aqueous and aqueous-organic biphasic systems.The effect of chain length on activity is very significant, the complex of VI-phosphos forming the most active catalyst.
