50559-10-9Relevant academic research and scientific papers
New DMSO-Based Reagents in Oxidation of Double and Triple Bonds and Synthesis of 1,2-Diketones
Yusubov, M. S.,Chi, Ki Whan,Krasnokutskaya, E. A.,Vasil'eva, V. P.,Filimonov, V. D.
, p. 1503 - 1506 (2007/10/03)
Preparative possibilities of oxidation of arylethenes and arylethynes using new reagents, iodine or palladium compounds in dimethylsulfoxide, in syntheses of 1,2-diketones are considered.The system PdCl2-Me2SO is shown to possess lower activity as compared to I2-Me2SO in oxidation of the double bonds, higher selectivity in oxidation of the triple bonds of diarylethynes and phenylpropyne, but more sensitive to steric effects of the substrate.
