50561-48-3Relevant academic research and scientific papers
Asymmetric induction using chiral 1,2,4-triazole arad benzimidazole derivatives
Katritzky, Alan R.,Aslan, Diana C.,Leeming, Peter,Steel, Peter J.
, p. 1491 - 1500 (2007/10/03)
Lithiated N-substituted 1,2,4-triazoles 3 and 8 and benzimidazole 11 reacted with (1R)-fenchone to give derivatives 5c, 9 and 12 in good yields as single diastereoisomers, (S)-Lactic acid 16 reacted with o-phenylenediamine 15 to give optically pure (S)-2-
Triazole Phosphonates. Electrophilic Substitution of 1-Substituted-1H-1,2,4-triazoles via Lithiated Triazole Intermediates
Anderson, D. Keith,Sikorski, James A.,Reitz, David B.,Pilla, Linda T.
, p. 1257 - 1262 (2007/10/02)
The metalation chemistry of several 1-substituted-1H-1,2,4-triazoles has been investigated.When various alkyl groups were incorporated in the 1-position, lithiation proceeded exclusively at C-5.The 1-trityl-, 1-methyl-, and 1-benzyl-5-lithio-1,2,4-triazol
