50614-19-2Relevant academic research and scientific papers
Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions
Gil-Negrete, José M.,Pérez Sestelo, José,Sarandeses, Luis A.
, p. 1453 - 1456 (2018)
Bench-stable solid triorganoindium compounds have been prepared by coordination with 4-(dimethylamino)pyridine (DMAP). The solid R3In(DMAP) complexes are obtained from the corresponding solution of R3In in quantitative yield and can
HOMOLYTIC ADDITION OF ALKYLPYRIDINES TO PHENYLACETYLENE
Il'yasov, E. A.,Galust'yan, G. G.,Asadova, M. G.
, p. 847 - 851 (2007/10/02)
The homolytic addition of 2-, 3-, and 4-methylpyridines and 2-methyl-5-ethylpyridine to phenylacetylene was studied under the conditions of peroxide initiation.The important role of polar factors in the reagents, affecting both the yields of 1-phenyl-3-pyridyl-1-alkenes and the ratio of cis and trans isomers, was demonstrated.
