50615-76-4Relevant academic research and scientific papers
Allylic strain as a stereocontrol element in the hydrogenation of 3-hydroxymethyl-cyclohex-3-en-1,2,5-triol derivatives. Synthesis of the carbasugar pseudo-2-deoxy-α-D-glucopyranose
Wen, Peng,Crich, David
, p. 5183 - 5191 (2018)
By adaptation of a literature method developed in the glucose series and standard protecting group manipulations a 2-deoxy-D-glucose derivative is converted to a series of 1R,2R,5R-3-hydroxymethyl-cyclohexen-1,2,5-triol derivatives whose reduction to the
Enzymatic synthesis of alkyl α-2-deoxyglucosides by alkyl alcohol resistant α-glucosidase from Aspergillus niger
Kim, Young-Min,Okuyama, Masayuki,Mori, Haruhide,Nakai, Hiroyuki,Saburi, Wataru,Chiba, Seiya,Kimura, Atsuo
, p. 403 - 409 (2007/10/03)
Aspergillus niger α-glucosidase (ANGase) was used for an efficient syntheses of alkyl α-d-2-deoxyglucosides (A2DGs) and for regioselectivity studies of alkoxy-hydro additions of d-glucal in the presence of alkyl alcohols. ANGase showed a high stability wi
Unusual stereoselectivity in sialic acid aldolase-catalyzed aldol condensations: Synthesis of both enantiomers of high-carbon monosaccharides
Lin, Chun-Hung,Sugai, Takeshi,Halcomb, Randall L.,Ichikawa, Yoshitaka,Wong, Chi-Huey
, p. 10138 - 10145 (2007/10/02)
An inversion of stereoselectivity in aldol condensations catalyzed by sialic acid aldolase (from Escherichia coli, Shinko American Inc.) was observed when L-mannose, 6-deoxy-L-mannose, L-talose, 2-deoxy-L-glucose, 2-deoxy-L-rhamnose, N-acetyl-L-mannosamin
