506417-30-7Relevant academic research and scientific papers
O-Vinyldiaryl- and O-vinylaryl(hetaryl)ketoximes: A breakthrough in O-vinyloxime chemistry
Zaitsev, Alexey B,Vasil'Tsov, Alexander M,Schmidt, Elena Yu,Mikhaleva, Al'Bina I,Morozova, Ludmila V,Afonin, Andrey V,Ushakov, Igor'A,Trofimov, Boris A
, p. 10043 - 10046 (2002)
O-Vinyldiarylketoximes and O-vinylaryl(hetaryl)ketoximes, a novel family of stable O-vinyloximes, are synthesized by a straightforward, unusually fast vinylation of diarylketoximes and aryl(hetaryl)ketoximes with acetylene in a superbase system of KOH-DMSO (60-80°C, 5-7min). Yields of up to 90% were obtained, thus introducing into organic synthesis a new group of highly promising building blocks and monomers.
