506417-41-0 Usage
Uses
1. Used in Chemical Synthesis:
DICHLOROBIS(2-(DIPHENYLPHOSPHINO)ETHYLA& is used as a catalyst for the synthesis of long chain linear fatty acid esters. Its ability to facilitate the formation of these esters makes it a valuable component in the production of various chemicals and materials.
2. Used in Hydrogenation Reactions:
In the field of organic chemistry, DICHLOROBIS(2-(DIPHENYLPHOSPHINO)ETHYLA& is used as a catalyst in the preparation of ruthenium borohydride complexes. These complexes are essential for carrying out hydrogenation reactions, which are crucial in the production of various pharmaceuticals, agrochemicals, and fine chemicals.
3. Used in Dehydrogenation of Ammonia Boranes:
DICHLOROBIS(2-(DIPHENYLPHOSPHINO)ETHYLA& is also employed as a catalyst in the dehydrogenation of ammonia boranes. This process is significant in the field of hydrogen storage and energy production, as it helps in the conversion of ammonia boranes into useful hydrogen sources.
4. Used in Chemoselective Reduction:
DICHLOROBIS(2-(DIPHENYLPHOSPHINO)ETHYLA& is used as a catalyst for the chemoselective reduction of carboxylic esters. This selective reduction is essential in the synthesis of specific organic compounds, as it allows for the preferential reduction of certain functional groups without affecting others.
5. Used in Synthesis of Ruthenium Beta-Aminophosphine Hydrazido/Chloro Complexes:
DICHLOROBIS(2-(DIPHENYLPHOSPHINO)ETHYLA& is utilized in the synthesis of ruthenium beta-aminophosphine hydrido/chloro complexes. These complexes exhibit catalytic activities in various chemical reactions, making them valuable in the development of new synthetic methods and processes.
Reaction
Efficient catalyst for the dihydrogen reduction of carboxylic esters and amides to alcohols.
Check Digit Verification of cas no
The CAS Registry Mumber 506417-41-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 5,0,6,4,1 and 7 respectively; the second part has 2 digits, 4 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 506417-41:
(8*5)+(7*0)+(6*6)+(5*4)+(4*1)+(3*7)+(2*4)+(1*1)=130
130 % 10 = 0
So 506417-41-0 is a valid CAS Registry Number.
InChI:InChI=1/2C14H16NP.2ClH.Ru/c2*15-11-12-16(13-7-3-1-4-8-13)14-9-5-2-6-10-14;;;/h2*1-10H,11-12,15H2;2*1H;/q;;;;+2/p-2
506417-41-0Relevant academic research and scientific papers
CATALYTIC CONVERSION OF CARBON DIOXIDE TO METHANOL
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Page/Page column 14, (2019/10/29)
The present disclosure relates to a new catalytic process for the production of methanol from carbon dioxide, comprising: (1) the conversion of carbon dioxide and hydrogen to formic acid or formate salts; (2) converting the formic acid or formate salts to diformate esters of diols; (3) hydrogenating the diformate esters to methanol and diols. The diols produced from the hydrogenation reaction can be recovered and re-used to prepare the diformate esters.
CATALYSTS AND PROCESSES FOR THE HYDROGENATION OF AMIDES
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Paragraph 0214; 0215; 0216, (2014/06/24)
There is provided a process for the reduction of one or more amide moieties in a compound comprising contacting the compound with hydrogen gas and a transition metal catalyst in the presence or absence of a base under conditions for the reduction an amide bond. The presently described processes can be performed at low catalyst loading using relatively mild temperature and pressures, and optionally, in the presence or absence of a base or high catalyst loadings using low temperatures and pressures and high loadings of base to effect dynamic kinetic resolution of achiral amides.
Hydrogenation of amides catalyzed by a combined catalytic system of a Ru complex with a zinc salt
Kita, Yusuke,Higuchi, Takafumi,Mashima, Kazushi
supporting information, p. 11211 - 11213 (2014/09/30)
Addition of catalytic amounts of zinc salts facilitated the hydrogenation of amides catalyzed by a ruthenium complex bearing 2-(diphenylphosphino) ethanamine (L1). The combined catalytic system of the ruthenium complex [RuCl2(L1)2] with a zinc salt such as Zn(OCOCF 3)2 mediated hydrogenation of various amides under mild conditions to afford the corresponding primary alcohols.
METHOD FOR PREPARING A METAL CATALYST
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Page/Page column 12, (2012/03/10)
The present disclosure relates to a method for preparing a metal catalyst comprising at least one ligand that is coordinated to the metal through at least one phosphorous (P) atom and at least one nitrogen (N) atom, the method comprising reacting a metal pre-cursor complex with an acid ad salt of an aminophosphine, diaminophosphine, aminodiphosphine or diaminodiphosphine, in the presence of a base.
