50673-31-9Relevant academic research and scientific papers
The infrared spectrum of aminodifluoroborane, NH2BF2: Partial assignment of the fundamentals and analysis of the 21/0 band near 1608 cm-1
Jemson, H. M.,Lewis-Bevan, W.,Gerry, M. C. L.
, p. 2088 - 2099 (2007/10/02)
The infrared spectrum of gas phase aminodifluoroborane, NH2BF2, has been observed for the first time.A partial assignment to the fundamental vibrations has been made.The 21/0 band has been recorded at high resolution, and the rotational and centrifugal distortion constants of NH211BF2 have been obtained in both the ground and 21 levels.A small rotational perturbation in the 21 level has been attributed to a perpendicular Coriolis interaction.Using a newly written least-squares fitting program, spectroscopic constants of the unseen level have been evaluated, including its band origin and the Coriolis coupling coefficient.Possible identities of the unseen level are suggested.
