50694-42-3Relevant academic research and scientific papers
Nickel-catalyzed insertions of vinylidenes into Si-H bonds
Biswas, Sourish,Pal, Sudipta,Uyeda, Christopher
, p. 14175 - 14178 (2020/11/24)
A nickel-catalyzed reductive cyclization of 1,1-dichloroalkenyl silanes is reported. The products of this reaction are unsaturated five-or six-membered silacycles. Intermolecular variants are also described, providing access to trisubstituted vinyl silanes that are not accessible by alkyne hydrosilylation or sila-Heck-type processes. A variety of silanes can be utilized, including those that serve as nucleophilic partners in Hiyama cross-coupling reactions. Mechanistic studies using deuterium-labelled silanes are described. This journal is
Construction of 2,3- and 3,4-functionalized silacyclopentanes: Synthesis of 6-aza-2,2-diphenyl-2-silabicyclo[3.1.0]hexane and 6-aza-3,3-diphenyl-3- silabicyclo[3.1.0]hexane derivatives
Mignani, Serge,Barreau, Michel,Damour, Dominique,Renaudon, Alain,Dejean, Valerie,Manuel, Georges
, p. 1163 - 1173 (2007/10/03)
The synthesis of five azasilabicyclo[3.1.0]hexanes containing an aziridine function in the α- or the β- position of the silicon atom is described. These bicyclic heterocompounds differ by the various substituents (H, Me, CO2Et, CPh3)
