50702-44-8

Upstream product

• 65755-26-2 2-Chloro-2-[N-(4-chloro-phenyl)aminosulfanyl]-1,2-diphenyl-ethanone 
• 1402072-34-7 (E)-2-((4-chlorophenyl)imino)-1,2-diphenylethanol 
• 106-47-8 4-chloro-aniline 
• 134-81-6 benzil 
• 63369-91-5 α-chloro-α-(chlorosulfenyl)benzyl phenyl ketone 

Downstream Products

• 181228-73-9 [Pd(C₆H₅COC(C₆H₄)NC₆H₄Cl)Cl]2 
• 158640-76-7 [Pd(C₆H₅COC(C₆H₄)NC₆H₄Cl)(CH₃CO₂)]2 
• 181061-15-4 [Pt(C₆H₅COC(C₆H₄)NC₆H₄Cl)Cl]2 
• 58268-11-4 erythro-2-<(p-chlorophenyl)amino>-1,2-diphenylethanol 
• 84197-59-1 4-Benzoyl-1-(4-chloro-phenyl)-3,4-diphenyl-azetidin-2-one 
• 87277-29-0 [4-(4-Chloro-phenyl)-3,5-diphenyl-4,5-dihydro-[1,2,4]oxadiazol-5-yl]-phenyl-methanone 
• 134225-88-0 1-Hydroxy-2-<(4-chlorophenyl)imino>-1,2-diphenylethyl thiophenol-2-amino 
• 134225-87-9 1-Hydroxy-2-<(4-chlorophenyl)imino>-1,2-diphenylethyl thiophenol 
• 58268-11-4 2-(4-chlorophenylamino)-1,2-diphenylethanol 
• 58268-09-0 2-[(4-chlorophenyl)amino]-1,2-diphenylethan-1-one 
• 141693-23-4 1,2-diphenyl-2-(phenylthio)-2-<(4-chlorophenyl)amino>-ethane-1-thione 
• 134225-89-1 1-Hydroxy-2-<(4-chlorophenyl)imino>-1,2-diphenylethyl diphenyl-phosphinodithioates 
• 87277-44-9 [4-(4-Chloro-phenyl)-5-phenyl-3-p-tolyl-4,5-dihydro-[1,2,4]oxadiazol-5-yl]-phenyl-methanone 
• 87288-17-3 [3,4-Bis-(4-chloro-phenyl)-5-phenyl-4,5-dihydro-[1,2,4]oxadiazol-5-yl]-phenyl-methanone 

Relevant academic research and scientific papers

Synthesis and oxidation of (E)-1,2-diphenyl-2-(arylimino) ethanol derivatives

The compounds (E)-1,2-diphenyl-2-(phenylimino)ethanol, (E)-1,2-diphenyl-2- (p-tolylimino)ethanol, and (E)-2-((4-chlorophenyl)imino)-1,2-diphenylethanol) were synthesized by reaction of a p-substituted aniline with benzoin then oxidized with chromium trioxide-triethylamine in chloroform to give (E)-1,2-diphenyl-2-(phenylimino)ethanone, (E)-1,2-diphenyl-2-(p-tolylimino) ethanone, and (E)-2-((4-chlorophenyl)imino)-1,2-diphenylethanone in very high yield. The products were characterized by IR and NMR spectral analysis.

Titanium(IV) chloride induced reactions of ketones and C-acylimines with dimethylcyanamide

The reactions of ketones (benzophenone, 4-methylbenzophenone, acetophenone, acetone, and 2,2,4,4-tetramethyl-3-pentanone) and C-acylimines with dimethylcyanamide in the presence of titanium(IV) chloride were investigated. Benzophenone and 4-methylbenzophenone react with dimethylcyanamide to give 4,4-disubstituted 2-dimethylamino-3-aza-1-oxa-1,3-butadienes 5 and 4,4-disubstituted 2-dimethylanuno-1-N,N-dimethylcarbamoyl-1,3-diaza-1,3-butadienes 9. Ketones with enolizable hydrogen atoms undergo aldol reactions under these conditions. C-Acylimines 11b-11e, derived from benzil and substituted anilines, undergo [2 + 2] cycloaddition to dimethylcyanamide with subsequent ring opening to 1-(N,N-dimethylcarbamoyl)-2,3,4-triaryl-1,4-diaza-1,3-butadienes 15. 1,2-Diphenyl-2-(isopropylimino)ethanone (11a) reacts with dimethylcyanamide to give 2-dimethylamino-1-isopropyl-4,4-diphenyl-2-imidazolin-5-one (23) in a hitherto unknown multistep reaction. The structure of 23 was confirmed by an X-ray analysis. VCH Verlagsgesellschaft mbH, 1996.

Stereochemistry of Imino-group Reduction. Part 3. The Hydride Reduction of Achiral Benzil Monoimines

The RR,SS:RS,SR ratio of diastereoisomeric amino-alcohols obtained from the lithium aluminium hydride reduction of the monoimines prepared by reaction of benzil and various aliphatic and aromatic achiral amines has been determined.Stereochemical results a