50707-36-3Relevant academic research and scientific papers
A new and efficient palladium-catalyzed synthesis of a 2,3,4,5- tetrahydro-1H-2,4-benzodiazepine-1,3-dione derivative
Bocelli, Gabriele,Catellani, Marta,Cugini, Federica,Ferraccioli, Raffaella
, p. 2623 - 2624 (2007/10/03)
The palladium-catalyzed intramolecular cyclization of 1-butyl-1(o- iodobenzyl)-3-phenylurea 1 at 80°C in the presence of carbon monoxide at atmospheric pressure gives the corresponding 2,3,4,5-tetrahydro-1H-2,4- benzodiazepine-1,3-dione derivative 2 in 91% yield. Yield and selectivity are strongly affected by the solvent.
ANODIC OXIDATION OF COMPOUNDS HAVING BENZYLIC OR ALLYLIC CARBON AND α-CARBON TO HETERO ATOM USING N-HYDROXYPHTHALIMIDE AS A MEDIATOR
Masui, Masaichiro,Hara, Seijiro,Ueshima, Takahiro,Kawaguchi, Tetsuo,Ozaki, Shigeko
, p. 4209 - 4212 (2007/10/02)
Benzylic, allylic carbons and the carbon α to hetero atoms are electrochemically oxidized to the corresponding carbonyl group in the presence of N-hydroxyphthalimide under mild conditions.KEYWORDS - anodic oxidation; mediator; N-hydroxyphthalimide; benzylic carbon; allylic carbon; ether; sulfide; amide
