50728-05-7Relevant academic research and scientific papers
DER OXIDATIVE ABBAU VON THIOPHOSPHIN- THIOPHOSPHON- UND THIOPHOSPHORSAEUREESTERN MIT HYPOCHLORIT
Horner, Leopold,Gerhard, Joachim
, p. 13 - 22 (2007/10/02)
The thioesters R1R2P(X)SR (X = O, S) 1 to 4 are degradated oxidatively forming R1R2P(O)OH and R-SO3H.The influence of the following parameters on the oxidation course is investigated using standard conditions: pH, concentration of the hypochlorite, quality of the organic phase and cooperation of phase transfer catalysts and hypochlorite cations.The thioesters 1 to 4 are degradated by hypochlorite with different rates depending on the type of the ligands R1 and R2 and the employment of an optimal pH.An analytical evaluation is possible.
