50743-12-9Relevant academic research and scientific papers
Phototransformations of C-benzoylaziridines. Dipolarophilic trapping of photogenerated azomethine ylides
Ramaian, D.,Muneer, M.,Gopidas, K. R.,Das, P. K.,Rath, N. P.,George, M. V.
, p. 4240 - 4246 (2007/10/03)
The phototransformations of a few 2,3-diaroylaziridines and 2-aryl-3-aroylaziridines have been studied by steady-state photolysis and product analysis.The formation of various photoproducts could be substantiated by ring opening via C-C bond cleavage (leading to azomethine ylides), intramolecular hydrogen abstraction, and C-N bond cleavage.Isolation of stereospecific 3-pyrrolidine derivatives from the photoreaction of benzoylaziridines in the presence of DMAD confirms our previous results concerning the azomethine ylides as major transient intermediates, produced under laser pulse photoexcitation.Dimethyl 1-cyclohexyl-2-benzoylpyrrole-3,4-dicarboxylate (25), one of the photoadducts derived from the reaction of 1a and 1b with DMAD undergoes a novel and unusual photoarrangement to give dimethyl 2-(1-benzoylcyclohexyl)pyrrole-3,4-dicarboxylate (27), the structure of which was confirmed through X-ray crystallographic analysis.
Addition de cyano-2 aziridines a quelques alcynes; obtention de pyrroles
Merah, Boumediene,Texier, Fernand
, p. 552 - 558 (2007/10/02)
Addition of the α-bromocinnamonitrile to primary amines (Cromwell method) leads to 2-cyano-3-phenyl-N-alkyl-aziridines, but the formation of the isomeric enamines always competes with this reaction.These aziridines, which are potential azomethine-ylids, a
