50767-77-6

Upstream product

• 123298-81-7 (1R,2R)-1,3,3-Trimethyl-2-[2-(2-methyl-[1,3]dioxolan-2-yl)-ethyl]-cyclohexanecarbaldehyde 
• 123298-78-2 (1S,2S)-1,3,3-Trimethyl-2-[2-(2-methyl-[1,3]dioxolan-2-yl)-ethyl]-cyclohexanecarboxylic acid 
• 123298-79-3 methyl t-2-<3,3-(ethylenedioxy)butyl>-1,3,3-trimethyl-r-1-cyclohexanecarboxylate 
• 123298-82-8 4-(2,2,6-trimethyl-t-6-vinylcyclohex-r-1-yl)-2-butanone ethylene acetal 

Relevant academic research and scientific papers

1,3-Diol Fragmentation Using a Reactive Benzylic Hydroxyl Group as a Nucleofuge. Synthesis of a Tobacco Sesquiterpene

A benzylic hydroxyl group activated by electron-donative aromatic function was found to be a remarkably reactive nucleofuge for 1,3-diol fragmentation.Thus, treatment of α-(2,6-dimethoxy-4-methylphenyl)-2β-hydroxy-2α,5,5,8aβ-tetramethyl-4aα-decahydro-1β-n

Remarkably Facile 1,3-Diol Fragmentation. Synthesis of a Seco-sesquiterpene of Tobacco

A benzylic hydroxyl group activated by the 2,6-dimethoxy-4-methylphenyl group was proved to be a remarkably reactive nucleofuge in 1,3-diol fragmentation under mild conditions. 4-(2,2,6-Trimethyl-6-vinylcyclohexyl)-2-butanone, a seco-sesquiterpene, was sy