50777-54-3

Basic information

• Product Name: 1-(3-(diphenylphosphoryl)phenyl)ethanone
• Synonyms: 1-(3-(diphenylphosphoryl)phenyl)ethanone
• CAS NO: 50777-54-3
• Molecular Weight: 320.328
• Mol File: 50777-54-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-(3-(diphenylphosphoryl)phenyl)ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(3-(diphenylphosphoryl)phenyl)ethanone(50777-54-3)
• EPA Substance Registry System: 1-(3-(diphenylphosphoryl)phenyl)ethanone(50777-54-3)

Safety Data

• Hazardous Substances Data: 50777-54-3(Hazardous Substances Data)

Upstream product

• 138313-22-1 3-acetylphenyl trifluoromethanesulfonate 
• 4559-70-0 Diphenylphosphine oxide 
• 14452-30-3 3'-iodoacetophenone 
• 2142-63-4 1-(3-Bromophenyl)ethanone 

Relevant articles and documents

Microwave assisted P–C coupling reactions without directly added P-ligands

Our group introduced a green protocol for the Pd(OAc)2- or NiCl2-catalyzed P–C coupling reaction of aryl halides and various > P(O)H-compounds under MW conditions without directly added P-ligands. The reactivity of a few aryl derivatives in the Pd(OAc)2-catalyzed Hirao reaction was also studied. An induction period was observed in the reaction of bromobenzene and diphenylphosphine oxide. Finally, the less known copper(I)-promoted P–C coupling reactions were investigated experimentally. The mechanism was explored by quantum chemical calculations.

Practical C–P bond formation via heterogeneous photoredox and nickel synergetic catalysis

An efficient C–P bond formation reaction was developed by virtue of the synergetic catalysis strategy by merging heterogeneous photocatalysis and nickel catalysis. This platform utilizing cadmium sulfide semiconductors as heterogeneous photocatalysts and