5080-24-0Relevant academic research and scientific papers
Synthesis and Reactions of N-Alkyl-O-diphenylphosphinylhydroxylamines and N-Alkyl-N-diphenylphosphinylhydroxylamines
Masse, Guy,Sturtz, Georges
, p. 904 - 907 (2007/10/02)
Reaction of a series of primary amines with bis(diphenylphosphinyl)peroxide conveniently leads to N-alkyl-O-diphenylphosphinylhydroxylamines.These compounds rearrange on heating to the thermodynamically more stable N-phosphinylated derivatives, the N-alkyl-N-diphenylphosphinylhydroxylamines (N-alkyldiphenylphosphinohydroxamic acids).
HYDROLYSIS REACTIONS IN LAMELLAR LIQUID CRYSTALLINE MEDIA ANC OCTANOL/WATER PARTITION COEFFICIENTS.
Bacon,Acree Jr.
, p. 177 - 184 (2007/10/02)
Cationic lamellar liquid crystalline morphologies decrease rates of hydrolysis of a series of 4-substituted benzylidene t-butylamine N-oxides as the electron releasing effect increases and they are linear when plotted against sigma ** plus -substituent constants. Rho-values indicate a more sensitive reactivity series in lamellar than in aqueous solvent. Reaction rates in the former solvent parallel the partition coefficients in octanol/water except for the methoxy-derivative.
