50880-48-3Relevant academic research and scientific papers
Base Catalysed Rearrangements Involving Ylide Intermediates. Part 10. The Effects of Torsional Strain in the Transition State upon and Rearrangements
Ollis, W. David,Sutherland, Ian O.,Thebtaranonth, Yodhathai
, p. 1963 - 1968 (2007/10/02)
The and sigmatropic rearrangements of the bicyclic ammonium ylides (8), (11), and (14) are inhibited by the bicyclic framework which prevents correct orbital alignment for ?-bonding in the transition state for a concerted sigmatropic rea
