509095-82-3Relevant academic research and scientific papers
Stereoelectronic and solvent effects on the allylic oxyfunctionalization of alkenes with singlet oxygen
Alberti, Mariza N.,Orfanopoulos, Michael
, p. 10660 - 10675 (2007/10/03)
The factors that control the stereochemistry of sensitized photooxygenation of alkenes via singlet oxygen (ene reaction) are selectively reported. We also introduce our most recent stereoelectronic effects on the singlet oxygen-ene reaction. The origin of
Ene hydroperoxidation of isobutenylarenes within dye-exchanged zeolite Na-Y: Control of site selectivity by cation-arene interactions
Stratakis, Manolis,Rabalakos, Constantinos,Mpourmpakis, Giannis,Froudakis, George E.
, p. 2839 - 2843 (2007/10/03)
The site selectivity in the singlet oxygen ene reaction of several deuterium-labeled isobutenylarenes depends on the position and the electronic nature of the aryl substitutents. For example, 1-(4-trifluoromethylphenyl)-2-methylpropene gives 82% twin sele
