50987-48-9Relevant academic research and scientific papers
In situ generation of n-butanethiol and its reaction with electron-deficient olefines
Gariani, Rogerio A.,Santos, Alcindo A. Dos,Comasseto, Joao V.
, p. 789 - 795 (2008)
n-Butanethiol is generated in situ by sequential addition of n-butyllithium and water to elemental sulfur. The n-butanethiol formed was reacted with electron-deficient olefines to give Michael-type addition products in good yields. The method avoids the manipulation of the bad-smelling n-butanethiol. Copyright Taylor & Francis Group, LLC.
Hydrochalcogenation of activated olefines. Synthesis of functionalized dialkylchalcogenides
Comasseto, Jo?o V.,Gariani, Rogério A.,Princival, Jefferson L.,Dos Santos, Alcindo A.,Zinn, Fabiano K.
, p. 2929 - 2936 (2008/12/21)
Alkanethiols, selenols and tellurols are generated in situ by reaction of elemental sulfur, selenium and tellurium with commercial alkyllithiums, followed by reaction with deoxygenated water. The alkanechalcogenols react in situ with activated olefins in a Michael-type addition reaction.
