50996-72-0

Basic information

• Product Name: ALLYL ISOPROPYL SULPHIDE
• Synonyms: 1-Propene, 3-[(1-methylethyl)thio]-;3-(Isopropylsulfanyl)-1-propene;ALLYL ISO-PROPYL SULFIDE;ALLYL ISOPROPYL SULPHIDE;3-[(1-Methylethyl)thio]-1-propene;Isopropylallyl sulfide
• CAS NO: 50996-72-0
• Molecular Formula: C₆H₁₂S
• Molecular Weight: 116.22
• Product Categories: monomer
• Mol File: 50996-72-0.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 134.4°C at 760 mmHg
• Flash Point: 25.5°C
• Appearance: /
• Density: 0.848g/cm³
• Vapor Pressure: 10mmHg at 25°C
• Refractive Index: 1.46
• CAS DataBase Reference: ALLYL ISOPROPYL SULPHIDE(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYL ISOPROPYL SULPHIDE(50996-72-0)
• EPA Substance Registry System: ALLYL ISOPROPYL SULPHIDE(50996-72-0)

Safety Data

• Statements: R11:Highly flammable.; R36/37/38:Irritating to eyes, respiratory system and skin.
• Safety Statements: S16:Keep away from sources of ignition - No smoking.; S26:In case of contact with eyes, rinse immediately with plenty of
• Hazardous Substances Data: 50996-72-0(Hazardous Substances Data)

Usage

Chemical compound

Allyl isopropyl sulphide

Found in

garlic, onions, and other members of the Allium genus

Contribution

pungent odor and flavor

Effects

irritating to eyes and mucous membranes when chopping or crushing

Studied for

potential health benefits, including antioxidant and anti-inflammatory properties
Potential protective effects against certain diseases

Investigated for

potential use as a flavoring agent and natural pesticide in agricultural applications
Versatile compound with a range of potential uses and benefits

InChI:InChI=1/C6H12S/c1-4-5-7-6(2)3/h4,6H,1,5H2,2-3H3

Upstream product

• 501014-38-6 allyl 2-phenylethyl carbonate 
• 75-33-2 2-propanethiol 
• 16308-68-2 allyl phenyl carbonate 
• 92822-58-7 allyl 2-phenylethylcarbonate 
• 14289-71-5 allyl diphenylmethylcarbonate 
• 76648-56-1 menthyl allyl carbonate 
• 1333925-48-6 allyl 4-(tert-butyldimethylsilyloxy)butylcarbonate 
• 1333925-44-2 1,2-isopropyliden-3-O-allyloxycarbonyl-sn-glycerin 
• 1333925-55-5 4-allyloxycarbonyloxybenzoic acid methyl ester 
• 16308-67-1 dodecyl allyl carbonate 
• 864530-59-6 (S)-2-allyloxycarbonylamino-3-(4-allyloxycarbonyloxyphenyl)propionic acid methyl ester 
• 1333925-60-2 (S)-2-allyloxycarbonylamino-3-allyloxycarbonyloxypropionic acid methyl ester 
• 1333925-61-3 methyl 6-O-allyloxycarbonyl-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 1333925-56-6 O-allyloxycarbonylmandelic acid ethyl ester 

Downstream Products

• 110890-32-9 (E)-(1R,2S)-1-Cyclohexyl-4-isopropylsulfanyl-2-triphenylsilanyl-but-3-en-1-ol 
• 95061-37-3 ((1Z,3E)-4-Isopropylsulfanyl-buta-1,3-dienyl)-cyclohexane 
• 141-05-9 Diethyl maleate 
• 3333-20-8 1-allyl-3-methylbenzene 
• 72087-71-9 1-(isopropylthio)-4-hydroxy-4-phenylpentene 
• 88915-93-9 erythro-3-(isopropylthio)-4-hydroxy-4-phenylpentene 
• 88916-19-2 threo-3-(isopropylthio)-4-hydroxy-4-phenylpentene 
• 88915-91-7 1-phenyl-4-(isopropylthio)-3-butenol 
• 85677-16-3 erythro-1-phenyl-2-(isopropylthio)-3-butenol 
• 85677-17-4 threo-1-phenyl-2-(isopropylthio)-3-butenol 
• 70600-08-7 1-<3-(isopropylthio)-2-propen-1-yl>cyclohexanol 
• 70600-06-5 1-<1-(isopropylthio)-2-propen-1-yl>cyclohexanol 
• 4756-05-2 thioacetone 
• 18001-18-8 allyldimethylphenylsilane 

Relevant articles and documents

A mild ligand-free iron-catalyzed liberation of alcohols from allylcarbonates

Different from most carbonates the allyloxy carbonyl protecting group can be cleaved under neutral conditions using metal catalysis. However, most of the catalysts employed to date are based upon precious metals. Herein we present two protocols for the mild Fe-catalyzed liberation of alcohols from allylcarbonates that are characterized by broad functional group tolerance and exclusive chemoselectivity.