511-20-6Relevant academic research and scientific papers
Facile Barton-McCombie deoxygenation of alcohols with tetrabutylammonium peroxydisulfate and formate ion
Hee, Sock Park,Hee, Yoon Lee,Yong, Hae Kim
, p. 3187 - 3190 (2007/10/03)
(Chemical Equation Presented) A new method for efficient radical deoxygenation of alcohols is described for preparing bulk chemicals avoiding scale-up problems. Treatment of various thiocarbonyl derivatives with (Bu 4N)2S2O8 and HCO2Na in DMF afforded the corresponding deoxygenated products in excellent yields. The deoxygenation appears to be initiated by the transfer of a single electron to thiocarbonyl derivatives from CO2?- rather than from SO4?-.
Marine sterols. XXI. Isolation of (24S)-3β-hydroxyergost-5-en-21-oic acid from a Sclerophytum sp. of soft coral
Kobayashi,Haribabu,Anjaneyulu
, p. 233 - 234 (2007/10/02)
The lipid extract of the Sclerophytum sp. of soft coral, collected off the coast of the Andaman and Nicobar Islands, afforded a new sterol 1a. The structure of 1a was shown to be (24S)-3β-hydroxyergost-5-en-21-oic acid, the first member of a class of mari
