51105-95-4Relevant academic research and scientific papers
A two-step synthesis of α-keto vinyl carbinols from ketones
Debien, Laurent,Zard, Samir Z.
, p. 6066 - 6069 (2013)
Conjugate addition of lithium enolates onto terminal alkynyl- and allenyl-sulfoxides furnishes the corresponding allylic sulfoxides. The latter readily undergo a Mislow-Braverman-Evans rearrangement to yield the targeted α-keto vinyl carbinols. This two-s
