51108-33-9

Basic information

• Product Name: N~3~,N~3~-dimethyl-1H-1,2,4-triazole-3,5-diamine
• CAS NO: 51108-33-9
• Molecular Formula: C₄H₉N₅
• Molecular Weight: 127.1478
• Mol File: 51108-33-9.mol

Chemical Properties

• Boiling Point: 324.1°C at 760 mmHg
• Flash Point: 149.8°C
• Density: 1.345g/cm³
• Vapor Pressure: 0.000251mmHg at 25°C
• Refractive Index: 1.673
• CAS DataBase Reference: N~3~,N~3~-dimethyl-1H-1,2,4-triazole-3,5-diamine(CAS DataBase Reference)
• NIST Chemistry Reference: N~3~,N~3~-dimethyl-1H-1,2,4-triazole-3,5-diamine(51108-33-9)
• EPA Substance Registry System: N~3~,N~3~-dimethyl-1H-1,2,4-triazole-3,5-diamine(51108-33-9)

Safety Data

• Hazardous Substances Data: 51108-33-9(Hazardous Substances Data)

Upstream product

• 51108-31-7 N-cyano-S,N¹,N¹-trimethylisothiourea 
• 131022-99-6 Methyl (3-dimethylamino-5-amino-1H-1,2,4-triazol-1-yl)dithiocarbonate 
• 60-34-4 methylhydrazine 

Downstream Products

• 3735-92-0 N,N,S-trimethyldithiocarbamate 
• 131023-12-6 methyl (3-dimethylamino-1,2,4-triazol-5-yl)aminodithiocarbonate 

Relevant articles and documents

On Triazoles. XXVIII. Synthesis of Isomeric 1,2,4-Triazolylcarbothiohydrazides

Different 3a, 3b, 9, 10 and 12 type 5-amino-1,2,4-triazolylcarbothiohydrazide isomers representing all possible isomeric types derived from 5-amino-1,2,4-triazoles were synthesised from the corresponding 5-amino-1,2,4-triazolyldithiocarbonates and hydrazines.HPLC measurements proved that in case of monosubstituted hydrazines the steric press in the intermediate 6 caused besides formation of the expected derivative 3a the formation of compounds 4 and 5, too, while the intermediate 7 yielded only 3b.Thermal rearangement of derivatives 3a in acetic acid led to isomers 9 and 10, respectively.

On Triazoles. V . Synthesis of 1- and 2-R1-3-R2,R3-Amino-5-amino-1,2,4-triazoles

The correct isomeric and tautomeric structure of different 1- and 2-R1-3-R2,R3-amino-5-amino-1,2,4-triazole derivatives prepared from the corresponding N-cyano-N'-R2,R3-S-methyl-isothioureas and the corresponding hydrazines was proved with the help of their ir, uv, 1H-nmr and 13C-nmr spectra as well as the uv spectra of the Schiff bases of an isomeric pair.