51117-92-1

Basic information

• Product Name: Benzene, 1,1'-[1-chloro-2-(methylthio)-1,2-ethenediyl]bis-, (E)-
• CAS NO: 51117-92-1
• Molecular Formula: C15H13ClS
• Molecular Weight: 260.787
• Mol File: 51117-92-1.mol

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-[1-chloro-2-(methylthio)-1,2-ethenediyl]bis-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-[1-chloro-2-(methylthio)-1,2-ethenediyl]bis-, (E)-(51117-92-1)
• EPA Substance Registry System: Benzene, 1,1'-[1-chloro-2-(methylthio)-1,2-ethenediyl]bis-, (E)-(51117-92-1)

Safety Data

• Hazardous Substances Data: 51117-92-1(Hazardous Substances Data)

Upstream product

• 917-54-4 methyllithium 
• 131968-40-6 N-(2-chloro-1,2-diphenylvinylthio)phthalimide 
• 5813-48-9 Methanesulfenyl chloride 
• 501-65-5 diphenyl acetylene 
• 67-68-5 dimethyl sulfoxide 
• 103-30-0 (E)-1,2-diphenyl-ethene 

Downstream Products

• 51117-93-2 trans-α-Chlor-α'-methylsulfonylstilben 

Relevant articles and documents

Phthalimidesulfenyl Chloride. Part 4. Addition to Acetylenes and Synthetic Utilization of their Adducts

Both the stereo- and regio-chemical reactivity of the phthalimidesulfenyl chloride 1 towards symmetrical and terminal acetylenes and the reactivity of the adducts 3 and 5 with various nucleophiles has been investigated.Nucleophilic substitution of the phthalimide residue was achieved with MeLi, PhLi, ButLi, (Me3Si)2NNa and Me3SiSMe.The synthesis of β-chlorovinyl tributylstannyl sulfides 14 is also described.The synthetic potential of the new sulfur compounds is discussed.