511256-90-9

Upstream product

• 511256-89-6 (2R,3S,4aR,6R,7R,8aR,9aS,10aS)-trifluoromethanesulfonic acid 3-(tert-butyldimethylsilanyloxy)-7-hydroxy-6-[3-(4-methoxybenzyloxy)propyl]-7,8a-dimethyloctahydropyrano[3,2-b]pyran-2-ylmethyl ester 
• 511256-95-4 (4aR,6S,7R,8S,8aR)-4-(4-methoxybenzyloxy)butyric acid 2,2-di(tert-butyl)-6-methyl-6-(2-methylallyl)-8-(trimethylsilanyloxy)-4,4a,6,7,8,8a-hexahydro-1,3,5-trioxa-2-silanaphthalen-7-yl ester 
• 511256-84-1 (4aR,6S,7R,8S,8aR)-4-(4-methoxybenzyloxy)butyric acid 2,2-di(tert-butyl)-8-hydroxy-6-methyl-6-(2-methylallyl)-4,4a,6,7,8,8a-hexahydro-1,3,5-trioxa-2-silanaphthalen-7-yl ester 
• 511256-86-3 (4aR,6S,7R,8aS)-2,2-di(tert-butyl)-7-{1-[3-(4-methoxybenzyloxy)propyl]vinyloxy}-6-methyl-6-(2-methylallyl)-4,4a,6,7,8,8a-hexahydro-1,3,5-trioxa-2-silanaphthalene 
• 511256-77-2 (4aR,6S,7R,8S,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-6-methyl-6-(2-methylallyl)-4,4a,6,7,8,8a-hexahydro-1,3,5-trioxa-2-silanaphthalen-7-ol 
• 511256-85-2 (4aR,6S,7R,8aS)-4-(4-methoxybenzyloxy)butyric acid 2,2-di(tert-butyl)-6-methyl-6-(2-methylallyl)-4,4a,6,7,8,8a-hexahydro-1,3,5-trioxa-2-silanaphthalen-7-yl ester 
• 511256-88-5 (4aR,6R,7S,8aR,9aS,10aS)-2,2-di(tert-butyl)-7-[3-(4-methoxybenzyloxy)propyl]-6,10a-dimethyl-octahydro-4H-1,3,8,10-tetraoxa-2-silaanthracen-6-ol 
• 511256-98-7 Trifluoro-methanesulfonic acid (2R,3S,4aR,6S,7R,8aS)-3,7-dihydroxy-6-[3-(4-methoxy-benzyloxy)-propyl]-7,8a-dimethyl-octahydro-pyrano[3,2-b]pyran-2-ylmethyl ester 
• 511256-87-4 (4aR,8aR,9aS,10aS)-2,2-di(tert-butyl)-7-[3-(4-methoxybenzyloxy)propyl]-6,10a-dimethyl-4a,5,8a,9,9a,10a-hexahydro-4H-1,3,8,10-tetraoxa-2-silaanthracene 
• 511256-97-6 (2S,3R,4aS,6R,7S,8aR)-6-Hydroxymethyl-2-[3-(4-methoxy-benzyloxy)-propyl]-3,4a-dimethyl-octahydro-pyrano[3,2-b]pyran-3,7-diol 
• 511256-76-1 (4aR,8R,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-6-methyl-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalene 
• 511256-94-3 (4aR,6S,7R,8S,8aR)-2,2-di(tert-butyl)-6-methyl-6-(2-methylallyl)-8-(trimethylsilanyloxy)-4,4a,6,7,8,8a-hexahydro-1,3,5-trioxa-2-silanaphthalen-7-ol 
• 511256-75-0 (4aR,8R,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalene 
• 511256-93-2 (4aR,6S,7R,8S,8aR)-2,2-di(tert-butyl)-6-methyl-6-(2-methylallyl)-4,4a,6,7,8,8a-hexahydro-1,3,5-trioxa-2-silanaphthalene-7,8-diol 

Downstream Products

• 511256-91-0 (2R,3S,4aR,6S,7R,8aS)-4-[3-(tert-butyldimethylsilanyloxy)-6-[3-(4-methoxybenzyloxy)propyl]-7,8a-dimethyl-7-(trimethylsilanyloxy)octahydropyrano[3,2-b]pyran-2-yl]butyraldehyde 
• 511257-00-4 4-{(2R,3S,4aR,6S,7R,8aS)-3-(tert-Butyl-dimethyl-silanyloxy)-6-[3-(4-methoxy-benzyloxy)-propyl]-7,8a-dimethyl-7-trimethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl}-butan-1-ol 

Relevant academic research and scientific papers

Synthesis of an F-H gambierol subunit using a C-glycoside-centered strategy

(Matrix presented) This manuscript describes our synthesis of the F-H subunit of gambierol. In addition to the synthesis of the tricycle, of note is an interesting protecting group influence on the generation of a C(23) C-glycoside as well as the use of r